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51.
Sedimentary processes in the paleocoastal part of the Bengal basin that occured in the Tertiary and Quaternary have been addressed. Three indicators were used: sedimentary bedding forms, microstructure of the sediment, and trace fossils. Various forms of sedimentary structures developed under the influence of dynamic geomorphic processes in the study area in the Quaternary. The microstructure analysis of the sedimentary materials was made by two methods: microphotography and Digital Color Analysis (DCA). The microstructure analysis shows that the geomorphic process remained very dynamic in the Quaternary, influencing the form, thickness, and mineral composition of the sediment strata. The enrichment of the sediments in heavy minerals evidences either oscillating or combined flow sedimentation, while under stable conditions light-mineral deposition took place. The digital data of microfabric study by the DCA method also show that larger particles deposited in the oscillating or high-flow environment and evidence a greater amount of heavy minerals like ferruginous materials. Trace fossils found in the sediments of this area also strongly support the concept that the environment remained dynamic during the Tertiary and Quaternary. The Late Tertiary deposition shows that, during these periods, the sediments were transported from tide-dominated marine coast with low flow energy, which is typical of hot and humid conditions. From Late Tertiary to Early Quaternary, the macrotidal coast became mesotidal (wave-dominated). The second phase is the Middle Pleistocene, when the environment was stable, favoring the continuous deposition of finer particles under low- to medium-flow energy conditions. The third phase, the Recent, is marked by the shoreline shift and modification of the environment. In the Early–Middle Holocene, the shoreline started to shift, which modified the geomorphic conditions of this place from coastal to estuarine and, finally, inland fluvial.  相似文献   
52.
Chromites occurring in different modes have been characterized from ophiolites of Rutland Island, a part of Burma-Andaman-Java subduction complex in the Bay of Bengal. Chromite mainly occurs as massive chromitite pods in mantle ultramafic tectonite and as thin massive chromitite bands together with minor disseminations in crustal ultramafic cumulate. Other than pods chromite also appears as: (a) anhedral restitic grains, (b) strings occurring as exsolved phases and as (c) symplectitic intergrowth with orthopyroxene in mantle tectonite. The chromites occurring as massive chromitite pods and bands contain high Cr (Cr#—73 to 80). Restitic chromite grains in mantle ultramafics are high-Mg (Mg#—58), high-Al (Al2O3—34 wt.%) and intermediate-Cr (Cr#—37) chromites. The bivariant plots of TiO2 wt.% vs 100Cr#, Mg# vs Cr# and Cr-Al-Fe3+ ternary discrimination diagram show that the massive and disseminated chromites fall in the boninitic field. The (Al2O3)melt and (FeO/MgO)melt values for the massive chromitites are estimated as 10 wt.% to 11 wt.% and 0.67–1.78 respectively, corroborating a boninitic parentage. Massive chromitite on Fe2+/Fe3+ vs Al2O3 wt.% and TiO2 wt.% vs Al2O3 wt.% plots occupy mainly the field of supra-subduction zone peridotites. High-Mg olivine (Fo91?93), high-Mg orthopyroxene (En~90) and high-Cr chromites of Rutland ophiolite are all supportive of boninitic source at supra-subduction zone setting. 57Fe Mössbauer study of chromite of beach placer shows that chromites occur in partly inverse spinel structure with iron distribution as Fe3+(A)Fe2+(A)Fe2+(B) which might be a result of oxidation. The olivine-spinel geothermometry shows 650–700°C re-equilibration temperature which is much lower than near crystallization temperature (950–1,050°C) derived from orthopyroxene-clinopyroxene assemblage. At supra-subduction setting an oxidizing hydrous fluid derived from subducting slab might have a major influence during the formation of Rutland ophiolite in this part of Burma-Java subduction complex.  相似文献   
53.
The use of coal fly ash and domestic sewage sludge in agriculture is being considered as one of the methods for recycling of these wastes in an environmental beneficial manner. Mixtures with soil were prepared at different proportions of fly ash and sludge, either alone or in combination at a maximum application rate of 52 t ha-1. The changes in the selected properties and heavy metal contents of three soil types in India were studied after incubating the respective mixtures for 90 days at near field capacity moisture level. Sewage sludge, due to its acidic and saline nature, high organic matter and heavy metals content, had more impact on soil properties than the fly ash. Sludge application produced several changes including an increase in available nitrogen, organic carbon, salinity and water-holding capacity of the soils. The concentrations of major cations and heavy metals also increased because of the sludge application and the pH was decreased. However, the levels of individual metal concentrations in all the mixture types were below the allowable limits prescribed by several environmental agencies. Using fly ash either alone or in equal quantity with sewage sludge had little influence on soil properties and heavy metal content. The relative availability (RA) of heavy metals in three soils amended with 52 t ha-1 of sewage sludge was observed to be highest in oxisol, followed by alfisol and vertisol.  相似文献   
54.
Two series of experiments were carried out with soft model-materials in order to assess the relative importance of initial homogeneous strain, external rotation and late-stage strain in reorienting early lineations during superposed buckle-folding. In the first series cylindrical buckling folds were produced in embedded planar sheets containing a “lineation”. In the second series noncylindrical folds were produced by compression of a set of cylindrical folds. The experiments indicate that the ratio of buckle shortening to layer-parallel strain is much smaller when the principal extension is parallel to the fold-axis than in the case when the principal extension is perpendicular to the fold-axis. In very competent rocks, the reorientation of old lineations is mainly by external rotation and by the associated concentric longitudinal strain. In moderately competent rocks, the orientation of early lineations always changes by initial homogeneous strain before buckling becomes significant. Because of the unlike amounts of initial strain in layers of different competences, orientations of unrolled lineations may not be parallel in disharmonically folded layers of unlike competences. Under certain conditions the early lineation may become virtually parallel to the later fold-axis. The experiments indicate that the effects of late-stage strain in buckle-folding are largely restricted to the incompetent layers of a multilayer. Hence, if orientation data of early lineations in both competent and incompetent rocks are lumped together, the pattern of orientation may become quite complex. Even for a single competent layer, the pattern of early lineations can locally become complex because of the complex nature of concentric longitudinal strain (and strain resulting from stretching of middle surface of the layer), development of conical folds, development of shear strain along hinge zones of deformed early folds and also because of the development of different orders of folds in both the first and the second deformations.  相似文献   
55.
56.
A number of troposphere-monitoring experiments were pressed into service during a large tropospheric disturbance which lasted for several days in December 1974. The experiments operated intensively included a monostatic Sodar system, a satellite radio beacon receiver at very low elevation angles, Meteorological Radiosondes, a 250-kW weather radar, a microwave LOS link and a microbarograph. This multi-pronged campaign yielded very useful results and the correspondences between various observations were striking. The Sodar and microwave link observations were visibly affected only when N reached a value of about –70 units; however, the satellite beacon observations showed anomalous behaviour even for lower N values. Rather spectacular coincidences occurred on one night: the large fading (up to 10 db) in the LOS link; highly disturbed conditions displayed in the entire Sodar range; the largest tropospheric effect on the satellite beacon system; and the most active superrefraction of the radar echoes. It was also noticed that these effects are obvious only during nights, while they remain masked or dampened in the sun-lit hours.  相似文献   
57.
Liquidus phase relationships in the CaAlAl–SiO6–Mg2SiO4–CaMgSi2O6–CaAlSi2O8 portion of the simplified basalt tetrahedron in the CaO–MgO–SiO2–Al2O3 system have been experimentally determined at 20 kbar pressure. The fo+di ss+sp+li univariant curve, that pierces the fo-di-an join and meets the fo+di ss+ enss+sp+li invariant point in the basalt tetrahedron, extends all the way to and pierces the di-fo-CaTs join, the limit of the simplified basalt tetrahedron toward the silica undersaturated portion.An algebraic method, relying on compositions of two successive liquids on a univariant curve and those of the crystalline phases in equilibrium with the respective liquids, is developed to identify the type of reaction that takes place along an isobarically univariant curve and to detect whether there is a temperature maximum on that curve. Use of this method for the di ss+fo+sp+li univariant equilibria shows that a temperature maximum exists on this curve at the composition Fo11Di56An3CaTs30, very close to and slighthly to the SiO2-rich side of the fo-di-CaTs join. The temperature along the univariant curve continuously decreases from the temperature maximum (1500°C) to the invariant point (1475°C) where the univariant curve is terminated by the appearance of e ss as a member of the equilibrium assemblage. Along this part of the curve, a reaction relationship occurs according to the equation fo+li=di ss+ sp. Compositions of di ss in equilibrium with the liquids from the temperature maximum to the fo+di ss+enss+ sp+li invariant point range from Di66En9CaTs25 to Di36En40CaTs24. Because of the reaction relationship of forsterite with liquid, fractional crystallization of a model alkalic basaltic liquid would cause liquids to move off the fo-di ss-sp-li univariant curve onto the sp-di ss divariant surface. Crystallization of di ss and sp would then lead to silica enrichment of residual liquids. Thus at pressures below 30 kbar, at which pressure the Al2O3–CaSiO3–MgSiO3 plane becomes a new thermal divide cutting through both the tholeiitic and alkalic volumes, alkalic liquids will fractionate toward tholeiitic compositions without crossing a thermal divide. This relationship would be expected to persist at pressures down to about 4 kbar where a maximum on the fo-di-an-li boundary line causes a thermal divide near the fo-di-an plane. Strongly SiO2-undersaturated liquids (e.g. nephelinites, basanites), on the other hand, cannot be derived from SiO2-undersaturated basalts (e.g. alkali olivine basalt) by fractional crystallization at 20 kbar. We also found that no gt primary phase volume cuts the wo-en-Al2O3 join at 20 kbar pressure. The wehrlite, the olivine clinopyroxenite, and the Al-augite group lherzolite xenoliths, containing highly aluminous clinopyroxenes (enriched in Ca-Tschermak), can be interpreted as crystal cumulates from alkalic basalts in the light of this experimental study. This is consistent with the mode of origin of these xenoliths proposed from petrographic, mineralogic, and geochemical studies.Abbreviations and notations di CaMgSi2O6 - fo Mg2SiO4 - an CaAl2Si2O8 - CaTs CaAlAlSiO6 - sp MgAl2O4 - en MgSiO3 - wo CaSiO3 - gt Ca3Al2Si3O12–Mg3Al2Si3O12 - qz SiO2 - li Liquid - gl glass - ss Solid Solution - A An mxn matrix - X A column vector - kbar kilobar  相似文献   
58.
We constructed a grid of relativistic models for standard high-relative-luminosity accretion α-disks around supermassive Kerr black holes (BHs) and computed X-ray spectra for their hot, effectively optically thin inner parts by taking into account general-relativity effects. They are known to be heated to high (~106–109 K) temperatures and to cool down through the Comptonization of intrinsic thermal radiation. Their spectra are power laws with an exponential cutoff at high energies; i.e., they have the same shape as those observed in active galactic nuclei (AGNs). Fitting the observed X-ray spectra of AGNs with computed spectra allowed us to estimate the fundamental parameters of BHs (their mass and Kerr parameter) and accretion disks (luminosity and inclination to the line of sight) in 28 AGNs. We show that the Kerr parameter for BHs in AGNs is close to unity and that the disk inclination correlates with the Seyfert type of AGN, in accordance with the unification model of activity. The estimated BH masses Mx are compared with the masses Mrev determined by the reverberation mapping technique. For AGNs with luminosities close to the Eddington limit, these masses agree and the model under consideration may be valid for them. For low-relative-luminosity AGNs, the differences in masses increase with decreasing relative luminosity and their X-ray emission cannot be explained by this model.  相似文献   
59.
 Amphiboles were synthesized from bulk compositions prepared along the join Ca1.8Mg5.2Si8O22(OH)2–Ca1.8Mg3Ga4Si6O22(OH)2 hydrothermally at 750–850 °C and 1.0–1.8 GPa, and along the join Ca2Mg5Si8O22F2–Ca2Mg3Ga4Si6O22F2, anhydrously at 1000 °C and 0.7 GPa to document how closely the tschermak-type substitution is obeyed in these analogues of aluminous amphiboles. Electron-microprobe analyses and Rietveld X-ray diffraction structure refinements were performed to determine cation site occupancies. The extent of Ga substitution was found to be limited in both joins, but with the fluorine series having about twice the Ga content (0.6 atoms per formula unit, apfu) of the hydroxyl-series amphiboles (0.3 apfu). The tschermak-type substitution was followed very closely in the hydroxyl series with essentially equal partitioning of Ga between tetrahedral and octahedral sites. The fluorine-series amphiboles deviated significantly from the tschermak-type substitution and, instead, appeared to follow a substitution that is close to a Ca-pargasite substitution of the type: [6]Ga3++2[4]Ga3++1/2[A] Ca2+ = [6]Mg2++2[4]Si4++1/2[A]□. Infrared spectroscopy revealed an inverse correlation between the intensity of the OH-stretching bands and the Ga content for the hydroxyl- and fluorine-series amphiboles. The direct correlation between the Ga and F content and inverse relationship between the Ga and OH content may be a general phenomenon present in other minerals and suggests, for example, that high F contents in titanite are controlled by the Al content of the host rock and that there may be similar direct Al–F correlations in tschermakitic amphiboles. Evidence for the possibility that Al (Ga) might substitute onto only a subset of the tetrahedral sites in tschermakitic amphiboles was sought but not observed in this study. Received: 5 March 2001 / Accepted: 31 July 2001  相似文献   
60.
The stratosphere holds a variety of particulates like polar stratospheric clouds (PSCs) and sulphate aerosols which catalyse chemical reactions. These reactions cause changes in the composition of the stratosphere, including the redistribution of active chlorine which might lead to ozone destruction. As a result during recent years a lot of effort has been directed towards the quantification of the uptake of trace gases like ClONO2, HCl, etc. into these particulates. However, it has been observed that many of the two and three dimensional models used in such studies are constrained by the lack of adequate rate constant data. This paper describes a theoretical approach to estimate the reaction rate constants for 23 gases on both types of polar stratospheric clouds (type I and II). It is found that for gases like N2O5, ClONO2 and HCl, diffusional uptake is important and contributes significantly to the heterogeneous reaction rate. A complete Lennard-Jones calculation is used to accurately compute the trace gas diffusion coefficients.  相似文献   
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